Bis[2-(2-pyridylmethyleneamino)benzenesulfonato]-κ3 N,N′,O;κ2 N,N′-copper(II)
نویسندگان
چکیده
In the mononuclear title compound, [Cu(C(12)H(9)N(2)O(3)S)(2)], the copper(II) salt of 2-(2-pyridylmethyl-eneamino)benzene-sulfonic acid, the Cu(II) atom is coordinated by one O and two N atoms from a monoanion as well as by two N atoms from another monoanion in a distorted trigonal-bipyramidal environment.
منابع مشابه
Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3 N,N′,O]zinc(II) dihydrate
In the title complex, [Zn(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, the Zn(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms and two O atoms from two tridentate 2-(2-pyridylmethyl-eneamino)benzene-sulfonate ligands in a slightly distorted octa-hedral environment. In the crystal structure, the complex forms a two-dimensional network through inter-molecular O-H⋯O and C-...
متن کاملBis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3 N,N′,O]cobalt(II) dihydrate
The title complex, [Co(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, has site symmetry 2 with the Co(II) cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyl-eneamino)benzene-sulfonate (paba) ligands chelate to the Co(II) cation in a distorted octa-hedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86 (13)°. Inter-molecular O-H⋯O ...
متن کاملBis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3 N,N′,O]manganese(II) dihydrate
The title complex, [Mn(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, is isotypic with the previously reported Zn(II) and Cd(II) species. The complex was prepared by the reaction of the potassium salt of 2-(2-pyridylmethyl-eneamino)benzene-sulfonic acid with MnCl(2)·6H(2)O in methanol. The complex displays twofold symmetry, with the ligands coordinated in a tridentate meridional-like arrangement through pyrid...
متن کاملBis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3 N,N′,O]cadmium(II) dihydrate
The title complex, [Cd(Paba)(2)]·2H(2)O or [Cd(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, was synthesized by the reaction of the potassium salt of 2-(2-pyridylmethyl-eneamino)benzene-sulfonic acid (PabaK) with CdCl(2)·2.5H(2)O in methanol. The Cd(II) atom lies on a crystallographic twofold axis and is coordinated by four N atoms and two O atoms from two deprotonated tridentate 2-(2-pyridylmethyl-eneamino)...
متن کاملBis(μ-3-carboxy-2-oxidobenzoato)-κ3O1,O 2:O 3;κ3 O 3:O1,O 2-bis[aqua(2,2′-bipyridine-κ2 N,N′)copper(II)]
In the centrosymmetric dinuclear complex, [Cu(2)(C(8)H(4)O(5))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Cu(II) ion is coordinated by two N atoms from a bipyridine ligand, three O atoms from two 3-carb-oxy-2-oxidobenzoate dianions and the O atom of the water mol-ecule in a distorted octa-hedral geometry. The Cu--O(H) coordination [2.931 (3) Å] is very weak. In the crystal structure, the dinuclear un...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009